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Please use this identifier to cite or link to this item: http://hdl.handle.net/2080/594

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contributor.authorMathur, Pradeep-
contributor.authorChatterjee, S-
contributor.authorDas, Atanau-
contributor.authorMobin, Shaikh M-
date.accessioned2008-02-01T06:57:40Z-
date.available2008-02-01T06:57:40Z-
date.issued2007-
identifier.citationJournal of Organometallic Chemistry , Vol 692, Iss 4, P 819-823en
identifier.urihttp://dx.doi.org/10.1016/j.jorganchem.2006.10.022-
identifier.urihttp://hdl.handle.net/2080/594-
descriptionCopyright for the article belongs to Elsevieren
description.abstractLow temperature photoreaction between tungsten hexacarbonyl and ferrocenylacetylene yielded two unusual metal containing stable compounds, the tritungsten cluster, [W3(μ-η2,η2- (H)Ctriple bond; length of mdashCFc)2(CO)12] (1), and ditungsten-1,4,5,8-ferrocenylcyclodecatetraene, [W2{μ-η2,η2,η2,η2-(Fc)Cdouble bond; length as m-dashC(H)C(H)double bond; length as m-dashC(Fc)C(Fc)double bond; length as m-dashC(H)C(H)double bond; length as m-dashC(Fc)}(CO)6] (2). Both compounds were characterised by IR and 1H and 13C NMR spectroscopy and their molecular structures established by single crystal X-ray diffraction methods.en
format.extent195789 bytes-
format.mimetypeapplication/pdf-
language.isoen-
publisherElsevieren
titlePhotochemical route to unusual tri-tungsten ferrocenylacetylene cluster [W3{-2,2-(H)CCFc}2(CO)12] and a dimetallacyclodecatetraene [W2{-2,22,2-(Fc)CC(H)C(H)=C(Fc)C(Fc)=C(H)C(H)=C(Fc)}(CO)6]en
typeArticleen
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