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| DC Field | Value | Language |
|---|
| contributor.author | Dinda, R | - |
| contributor.author | Ciobanu, Oxana | - |
| contributor.author | Wadephol, Heubert | - |
| contributor.author | Hubner, Olaf | - |
| contributor.author | Acharyya, Rama | - |
| contributor.author | Himmel, Hans-Jorg | - |
| date.accessioned | 2007-12-07T05:17:45Z | - |
| date.available | 2007-12-07T05:17:45Z | - |
| date.issued | 2007 | - |
| identifier.citation | Angewandte Chemie International Edition, Vol 46, P 9110 –9113 | en |
| identifier.uri | http://dx.doi.org/10.1002/anie.200703616 | - |
| identifier.uri | http://hdl.handle.net/2080/562 | - |
| description | Copyright belongs to Wiley | en |
| description.abstract | A number of boronium ions with the general formula [R2BL2]+ (where L is a donor, such as an amine), some borenium [R2BL]+, and even borinium [R2B]+ ions have been synthesized and structurally characterized.[1] In all these compounds, boron has a formal oxidation state of +III. In addition to the academic interest in the bonding properties in these species, some of them have found application as catalysts in polymerization[2] or Diels-Alder reactions.[3] Boronium cations are also efficient initiators for the dehydrogenation of ammonia-borane.[4] The boron atom of the boronium ions is more or less tetrahedrally coordinated by the two substituents R (for example, amido groups) and two donor ligands L (such as pyridine). In contrast, uncoordinated borinium species, such as the (dimethylamido)(2,2,6,6-tetramethylpiperidino)boron cation,[5] feature an almost linear NBN unit | en |
| format.extent | 1126113 bytes | - |
| format.mimetype | application/pdf | - |
| language.iso | en | - |
| publisher | Wiley | en |
| title | Synthesis and Structural Characterization of a Stable Dimeric Boron(II) Dication | en |
| type | Article | en |
| Appears in Collections: | Journal Articles
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| dinda.pdf | | 1099Kb | Adobe PDF | View/Open |
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