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Please use this identifier to cite or link to this item: http://hdl.handle.net/2080/562

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contributor.authorDinda, R-
contributor.authorCiobanu, Oxana-
contributor.authorWadephol, Heubert-
contributor.authorHubner, Olaf-
contributor.authorAcharyya, Rama-
contributor.authorHimmel, Hans-Jorg-
date.accessioned2007-12-07T05:17:45Z-
date.available2007-12-07T05:17:45Z-
date.issued2007-
identifier.citationAngewandte Chemie International Edition, Vol 46, P 9110 –9113en
identifier.urihttp://dx.doi.org/10.1002/anie.200703616-
identifier.urihttp://hdl.handle.net/2080/562-
descriptionCopyright belongs to Wileyen
description.abstractA number of boronium ions with the general formula [R2BL2]+ (where L is a donor, such as an amine), some borenium [R2BL]+, and even borinium [R2B]+ ions have been synthesized and structurally characterized.[1] In all these compounds, boron has a formal oxidation state of +III. In addition to the academic interest in the bonding properties in these species, some of them have found application as catalysts in polymerization[2] or Diels-Alder reactions.[3] Boronium cations are also efficient initiators for the dehydrogenation of ammonia-borane.[4] The boron atom of the boronium ions is more or less tetrahedrally coordinated by the two substituents R (for example, amido groups) and two donor ligands L (such as pyridine). In contrast, uncoordinated borinium species, such as the (dimethylamido)(2,2,6,6-tetramethylpiperidino)boron cation,[5] feature an almost linear NBN uniten
format.extent1126113 bytes-
format.mimetypeapplication/pdf-
language.isoen-
publisherWileyen
titleSynthesis and Structural Characterization of a Stable Dimeric Boron(II) Dicationen
typeArticleen
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