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Please use this identifier to cite or link to this item: http://hdl.handle.net/2080/339

Title: Synthesis and characterization of sol–gel derived ZrO2 doped Al2O3 nanopowder
Authors: Sarkar, D
Mohapatra, Deepak
Ray, S
Bhattacharyya, S
Adak, S
Mitra, N
Keywords: Alumina–zirconia
Hydrogel
Crystallization
FTIR
TEM
Issue Date: 2006
Publisher: Elsevier
Citation: Ceramics International (Accepted)
Abstract: Al2O3–ZrO2 composite gel precursor powder containing 5–15 mol% ZrO2 was prepared by wet chemical route. The washed gel containing pseudoboehmite and amorphous zirconia was characterized with respect to DTA/TG, XRD and IR spectroscopy. The DTA/TG result indicates three-stage decomposition for pseudoboehmite and single stage decomposition for amorphous zirconia. In the calcined powder phase evolution of Al2O3 follows the sequence pseudoboehmite → bayerite → boehmite → γ-Al2O3 → θ-Al2O3 → α-Al2O3, while that of ZrO2 follows amorphous ZrO2 → t-ZrO2 → (t + m)ZrO2. FTIR studies revealed that the number of M–OH and M–O bond increase on increasing mol% of ZrO2 due to a change in the cationic charge of the composite powder. TEM photograph of calcined powder showed both dispersed nano-size spherical particle as well as agglomerated particles. EPMA confirmed the near uniform distribution of zirconia particles in the alumina matrix.
Description: Copyright for this article belongs to Elsevier doi:10.1016/j.ceramint.2006.05.002
URI: http://hdl.handle.net/2080/339
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