“A Jack of Trio”- Facile One-pot Metal Free Oxidative Amination, Azidation and Peroxidation of Phenols

Abstract

A highly efficient methodology for generation of nitrogen containing Quarternary Carbon centres via aminative and azidative oxidative dearomatization of phenols has been explored. The same protocol has also been succesfully employed to achieve oxidative peroxidation of Phenols. The simplest metal free reaction conditions delineates an easy break through to the “Trio”- of oxidative amination, azidation and peroxidation. An array of diverse polyfunctionalised heterocycles has been synthesized in one pot