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| DC Field | Value | Language |
|---|
| contributor.author | Dinda, R | - |
| contributor.author | Majhi, P K | - |
| contributor.author | Sengupta, P | - |
| contributor.author | Pasayat, S | - |
| contributor.author | Ghosh, S | - |
| contributor.author | Falvello, L R | - |
| contributor.author | Mak, T C W | - |
| date.accessioned | 2010-01-25T22:01:45Z | - |
| date.available | 2010-01-25T22:01:45Z | - |
| date.issued | 2010 | - |
| identifier.citation | Journal of Polyhedron, Volume 29, Issue 1, 13 January 2010, Pages 248-253 | en |
| identifier.uri | http//dx.doi.org/http://dx.doi.org/10.1016/j.poly.2009.08.008 | - |
| identifier.uri | http://hdl.handle.net/2080/1160 | - |
| description.abstract | The syntheses and characterization of alkali metal complexes [{VO2L}M(H2O}n] (1 & 2)
[M = Na+ (1), K+ (2)] of anionic cis-dioxovanadium(V) species (LVO2 -) of the Schiff base
2-hydroxybenzoylhydrazone of 2-hydroxybenzaldehyde have been reported. The number of coordinated water molecules in [{VO2L}M(H2O}n] decreases as the charge density of the alkali metal ion decreases (n = 5 for Na+ and 1 for K+). These compounds represented M+-mediated
supramolecular assembly [{VO2L}M(H2O}n]∝ with an infinite polymeric structure containing an
alternating array of cis-dioxo vanadium(V), [VO2L]-, units and aquated metal ion centres, as
confirmed by X-ray crystallographic investigation of both. All the compounds are characterized
by elemental analysis, IR, UV-Vis and NMR spectroscopy. | en |
| format.extent | 790325 bytes | - |
| format.mimetype | application/pdf | - |
| language.iso | en | - |
| publisher | Elsevier | en |
| subject | Tridentate ONO donor ligand | en |
| subject | Oxovanadium(V) complexes | en |
| subject | X-ray crystal structure | en |
| subject | Alkali metal ion mediated supramolecular assembly | en |
| title | Alkali Metal (Na+ and K+)-Mediated Supramolecular Assembly of Oxovanadium(V) Complexes: Synthesis and Structural Characterization | en |
| type | Article | en |
| Appears in Collections: | Journal Articles
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| Manuscript-revised.pdf | | 771Kb | Adobe PDF | View/Open |
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