Please use this identifier to cite or link to this item:
Full metadata record
DC FieldValueLanguage
dc.contributor.authorDinda, R-
dc.contributor.authorMajhi, P K-
dc.contributor.authorSengupta, P-
dc.contributor.authorPasayat, S-
dc.contributor.authorGhosh, S-
dc.contributor.authorFalvello, L R-
dc.contributor.authorMak, T C W-
dc.identifier.citationJournal of Polyhedron, Volume 29, Issue 1, 13 January 2010, Pages 248-253en
dc.description.abstractThe syntheses and characterization of alkali metal complexes [{VO2L}M(H2O}n] (1 & 2) [M = Na+ (1), K+ (2)] of anionic cis-dioxovanadium(V) species (LVO2 -) of the Schiff base 2-hydroxybenzoylhydrazone of 2-hydroxybenzaldehyde have been reported. The number of coordinated water molecules in [{VO2L}M(H2O}n] decreases as the charge density of the alkali metal ion decreases (n = 5 for Na+ and 1 for K+). These compounds represented M+-mediated supramolecular assembly [{VO2L}M(H2O}n]∝ with an infinite polymeric structure containing an alternating array of cis-dioxo vanadium(V), [VO2L]-, units and aquated metal ion centres, as confirmed by X-ray crystallographic investigation of both. All the compounds are characterized by elemental analysis, IR, UV-Vis and NMR spectroscopy.en
dc.format.extent790325 bytes-
dc.subjectTridentate ONO donor liganden
dc.subjectOxovanadium(V) complexesen
dc.subjectX-ray crystal structureen
dc.subjectAlkali metal ion mediated supramolecular assemblyen
dc.titleAlkali Metal (Na+ and K+)-Mediated Supramolecular Assembly of Oxovanadium(V) Complexes: Synthesis and Structural Characterizationen
Appears in Collections:Journal Articles

Files in This Item:
File Description SizeFormat 
Manuscript-revised.pdf771.8 kBAdobe PDFView/Open

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.