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DC Field | Value | Language |
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dc.contributor.author | Mathur, Pradeep | - |
dc.contributor.author | Chatterjee, S | - |
dc.contributor.author | Das, Atanau | - |
dc.contributor.author | Mobin, Shaikh M | - |
dc.date.accessioned | 2008-02-01T06:57:40Z | - |
dc.date.available | 2008-02-01T06:57:40Z | - |
dc.date.issued | 2007 | - |
dc.identifier.citation | Journal of Organometallic Chemistry , Vol 692, Iss 4, P 819-823 | en |
dc.identifier.uri | http://dx.doi.org/10.1016/j.jorganchem.2006.10.022 | - |
dc.identifier.uri | http://hdl.handle.net/2080/594 | - |
dc.description | Copyright for the article belongs to Elsevier | en |
dc.description.abstract | Low temperature photoreaction between tungsten hexacarbonyl and ferrocenylacetylene yielded two unusual metal containing stable compounds, the tritungsten cluster, [W3(μ-η2,η2- (H)Ctriple bond; length of mdashCFc)2(CO)12] (1), and ditungsten-1,4,5,8-ferrocenylcyclodecatetraene, [W2{μ-η2,η2,η2,η2-(Fc)Cdouble bond; length as m-dashC(H)C(H)double bond; length as m-dashC(Fc)C(Fc)double bond; length as m-dashC(H)C(H)double bond; length as m-dashC(Fc)}(CO)6] (2). Both compounds were characterised by IR and 1H and 13C NMR spectroscopy and their molecular structures established by single crystal X-ray diffraction methods. | en |
dc.format.extent | 195789 bytes | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | en | - |
dc.publisher | Elsevier | en |
dc.title | Photochemical route to unusual tri-tungsten ferrocenylacetylene cluster [W3{-2,2-(H)CCFc}2(CO)12] and a dimetallacyclodecatetraene [W2{-2,22,2-(Fc)CC(H)C(H)=C(Fc)C(Fc)=C(H)C(H)=C(Fc)}(CO)6] | en |
dc.type | Article | en |
Appears in Collections: | Journal Articles |
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File | Description | Size | Format | |
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J-Organomet-Chem-2007-692-819.pdf | 191.2 kB | Adobe PDF | View/Open |
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