Please use this identifier to cite or link to this item: http://hdl.handle.net/2080/3885
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dc.contributor.authorBishi, Sangita-
dc.date.accessioned2023-01-10T12:29:39Z-
dc.date.available2023-01-10T12:29:39Z-
dc.date.issued2022-12-
dc.identifier.citation59th Annual Convention of Chemists 2022(ACC-2022) International Conference on Recent Trends in Chemical Sciences-2022 (RTCS-2022), IIT(ISM) Dhanbad, 16-18 December 2022en_US
dc.identifier.urihttp://hdl.handle.net/2080/3885-
dc.descriptionCopyright belongs to proceeding publisheren_US
dc.description.abstractThe Grignard reaction is an organometallic chemical reaction in which alkyl, allyl, vinyl, or aryl magnesium halides (Grignard reagent) is added to a carbonyl group in an aldehyde or ketone.1 We demonstrated a metal free heterogeneous organic semiconductor g-C3N4 catalysed2,3 and visible light-assisted benzylation of carbonyl moiety. A facile reaction results in the construction of C−C bonds4 under mild conditions in blue LED irradiation. The catalysis initiates via a radical pathway and involves a ketyl radical anion intermediate.5 The reaction shows good functional group tolerance with excellent yields. The strategy provides an easy access to these molecules with potential medicinal chemistry applications.en_US
dc.subjectPhoto-Decarboxylative Functionalizationen_US
dc.subjectBenzylic C(Sp3)-Hen_US
dc.subjectcarbonyl moietyen_US
dc.titleg-C3N4 Catalyzed Photo-Decarboxylative Functionalization of Benzylic C(Sp3)-H with carbonyl moiety: - An Alternative of Grignard’s Reactionen_US
dc.typePresentationen_US
Appears in Collections:Conference Papers

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