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http://hdl.handle.net/2080/3885
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DC Field | Value | Language |
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dc.contributor.author | Bishi, Sangita | - |
dc.date.accessioned | 2023-01-10T12:29:39Z | - |
dc.date.available | 2023-01-10T12:29:39Z | - |
dc.date.issued | 2022-12 | - |
dc.identifier.citation | 59th Annual Convention of Chemists 2022(ACC-2022) International Conference on Recent Trends in Chemical Sciences-2022 (RTCS-2022), IIT(ISM) Dhanbad, 16-18 December 2022 | en_US |
dc.identifier.uri | http://hdl.handle.net/2080/3885 | - |
dc.description | Copyright belongs to proceeding publisher | en_US |
dc.description.abstract | The Grignard reaction is an organometallic chemical reaction in which alkyl, allyl, vinyl, or aryl magnesium halides (Grignard reagent) is added to a carbonyl group in an aldehyde or ketone.1 We demonstrated a metal free heterogeneous organic semiconductor g-C3N4 catalysed2,3 and visible light-assisted benzylation of carbonyl moiety. A facile reaction results in the construction of C−C bonds4 under mild conditions in blue LED irradiation. The catalysis initiates via a radical pathway and involves a ketyl radical anion intermediate.5 The reaction shows good functional group tolerance with excellent yields. The strategy provides an easy access to these molecules with potential medicinal chemistry applications. | en_US |
dc.subject | Photo-Decarboxylative Functionalization | en_US |
dc.subject | Benzylic C(Sp3)-H | en_US |
dc.subject | carbonyl moiety | en_US |
dc.title | g-C3N4 Catalyzed Photo-Decarboxylative Functionalization of Benzylic C(Sp3)-H with carbonyl moiety: - An Alternative of Grignard’s Reaction | en_US |
dc.type | Presentation | en_US |
Appears in Collections: | Conference Papers |
Files in This Item:
File | Description | Size | Format | |
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2022_RTCS_SBishi_g-C3N4.pdf | 1.28 MB | Adobe PDF | View/Open |
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