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DC Field | Value | Language |
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dc.contributor.author | Dinda, R | - |
dc.contributor.author | Majhi, P K | - |
dc.contributor.author | Sengupta, P | - |
dc.contributor.author | Pasayat, S | - |
dc.contributor.author | Ghosh, S | - |
dc.contributor.author | Falvello, L R | - |
dc.contributor.author | Mak, T C W | - |
dc.date.accessioned | 2010-01-25T22:01:45Z | - |
dc.date.available | 2010-01-25T22:01:45Z | - |
dc.date.issued | 2010 | - |
dc.identifier.citation | Journal of Polyhedron, Volume 29, Issue 1, 13 January 2010, Pages 248-253 | en |
dc.identifier.uri | http//dx.doi.org/http://dx.doi.org/10.1016/j.poly.2009.08.008 | - |
dc.identifier.uri | http://hdl.handle.net/2080/1160 | - |
dc.description.abstract | The syntheses and characterization of alkali metal complexes [{VO2L}M(H2O}n] (1 & 2) [M = Na+ (1), K+ (2)] of anionic cis-dioxovanadium(V) species (LVO2 -) of the Schiff base 2-hydroxybenzoylhydrazone of 2-hydroxybenzaldehyde have been reported. The number of coordinated water molecules in [{VO2L}M(H2O}n] decreases as the charge density of the alkali metal ion decreases (n = 5 for Na+ and 1 for K+). These compounds represented M+-mediated supramolecular assembly [{VO2L}M(H2O}n]∝ with an infinite polymeric structure containing an alternating array of cis-dioxo vanadium(V), [VO2L]-, units and aquated metal ion centres, as confirmed by X-ray crystallographic investigation of both. All the compounds are characterized by elemental analysis, IR, UV-Vis and NMR spectroscopy. | en |
dc.format.extent | 790325 bytes | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | en | - |
dc.publisher | Elsevier | en |
dc.subject | Tridentate ONO donor ligand | en |
dc.subject | Oxovanadium(V) complexes | en |
dc.subject | X-ray crystal structure | en |
dc.subject | Alkali metal ion mediated supramolecular assembly | en |
dc.title | Alkali Metal (Na+ and K+)-Mediated Supramolecular Assembly of Oxovanadium(V) Complexes: Synthesis and Structural Characterization | en |
dc.type | Article | en |
Appears in Collections: | Journal Articles |
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Manuscript-revised.pdf | 771.8 kB | Adobe PDF | View/Open |
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